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CHEMISTRY Syllabus All

CHEMISTRY SYLLABUS ALL
CONTENTS OF CLASS XI SYLLABUS
UNIT I: Some Basic Concepts of Chemistry
• General Introduction:Important and scope of chemistry.
• Laws of chemical combination, Dalton’s atomic theory: concept of elements, atoms and molecules.
• Atomic and molecular masses. Mole concept and molar mass; percentage composition and empirical and molecular formula; chemical reactions, stoichiometry and calculations based on stoichiometry.
UNIT II: Structure of Atom
• Atomic number, isotopes and isobars. Concept of shells and subshells, dual nature of matter and light, de Broglie’s relationship, Heisenberg uncertainty principle, concept of orbital, quantum numbers, shapes of s,p and d orbitals, rules for filling electrons in orbitals- Aufbau principle, Pauli exclusion principles and Hund’s rule, electronic configuration of atoms, stability of half filled and completely filled orbital’s.
UNIT III: Classification of Elements and Periodicity in Properties
• Modern periodic law and long form of periodic table, periodic trends in properties of elements- atomic radii, ionic radii, ionization enthalpy, electron gain enthalpy, electronegativity, valence.
UNIT IV: Chemical Bonding and Molecular Structure
• Valence electrons, ionic bond, covalent bond, bond parameters, Lewis structure, polar character of covalent bond, valence bond theory, resonance, geometry of molecules, VSEPR theory, concept of hybridization involving s, p and d orbitals and shapes of some simple molecules, molecular orbital theory of homonuclear diatomic molecules (qualitative idea only). Hydrogen bond.
UNIT V: States of Matter: Gases and Liquids
• Three states of matter, intermolecular interactions, types of bonding, melting and boiling points, role of gas laws of elucidating the  concept  of  the  molecule,  Boyle’s  law,  Charle’s  law,  Gay  Lussac’s  law,  Avogadro’s  law,  ideal  behaviour  of  gases,  empirical derivation  of  gas  equation.  Avogadro number, ideal gas equation. Kinetic energy  and  molecular  speeds  (elementary  idea),
deviation from ideal behaviour, liquefaction of gases, critical temperature.
• Liquid State- Vapour pressure, viscosity and surface tension (qualitative idea only, no mathematical derivations).
UNIT VI: Thermodynamics
• First law of thermodynamics-internal energy and enthalpy, heat capacity and specific heat, measurement of ∆U and ∆H, Hess’s law  of  constant  heat summation,  enthalpy  of  : bond  dissociation, combustion, formation, atomization,  sublimation, phase transition, ionization, solution and dilution.
• Introduction  of  entropy  as  state  function,  Second  law  of  thermodynamics,  Gibbs  energy  change  for  spontaneous  and non spontaneous process, criteria for equilibrium and spontaneity.
• Third law of thermodynamics- Brief introduction.
UNIT VII: Equilibrium
• Equilibrium  in  physical  and  chemical  processes,  dynamic  nature  of  equilibrium,  law  of  chemical  equilibrium,  equilibrium constant, factors affecting equilibrium-Le Chatelier’s principle; ionic equilibrium- ionization of acids and bases, strong and weak electrolytes, degree of ionization, ionization of polybasic acids, acid strength, concept of PH., Hydrolysis of salts (elementary idea), buffer solutions, Henderson equation, solubility product, common ion effect (with illustrative examples).
UNIT VIII: Redox Reactions
• Concept of oxidation and oxidation and reduction, redox reactions oxidation number, balancing redox reactions in terms of loss and gain of electron and change in oxidation numbers.
UNIT IX: Hydrogen
• Occurrence,  isotopes,  preparation,  properties  and  uses  of  hydrogen;  hydrides-ionic,  covalent  and  interstitial;  physical  and chemical properties of water, heavy water; hydrogen peroxide-preparation, reactions, uses and structure;
UNIT X: s-Block Elements (Alkali and Alkaline earth metals)
• Group I and group 2 elements:
• General introduction, electronic configuration, occurrence, anomalous properties of the first element of each group, diagonal relationship, trends in the variation of properties (such as ionization enthalpy, atomic and ionic radii), trends in chemical reactivity with oxygen, water, hydrogen and halogens; uses.
• Preparation and Properties of Some important Compounds:
• Sodium carbonate, sodium chloride, sodium hydroxide and sodium hydrogencarbonate, biological importance of sodium and potassium.
• Industrial use of lime and limestone, biological importance of Mg and Ca.
UNIT XI: Some p-Block Elements
• General Introduction to p-Block Elements.
• Group 13 elements: General introduction, electronic configuration, occurrence, variation of properties, oxidation states, trends in chemical reactivity, anomalous properties of first element of the group; Boron, some important compounds: borax, boric acids, boron hydrides. Aluminium: uses, reactions with acids and alkalies.
• General 14 elements: General introduction, electronic configuration, occurrence, variation of properties, oxidation states, trends in chemical reactivity, anomalous behaviour of first element. Carbon, allotropic forms, physical and chemical properties: uses of some important compounds: oxides.
• Important compounds of silicon and a few uses: silicon tetrachloride, silicones, silicates and zeolites, their uses.
UNIT XII: Organic Chemistry- Some Basic Principles and Techniques
• General introduction, methods of purification qualitative and quantitative analysis, classification and IUPAC nomenclature of organic compounds.
• Electronic displacements in a covalent bond: inductive effect, electromeric effect, resonance and hyper conjugation.
• Homolytic and heterolytic fission of a covalent bond: free radials, carbocations, carbanions; electrophiles and nucleophiles, types of organic reactions.
UNIT XIII: Hydrocarbons
• Alkanes- Nomenclature, isomerism, conformations (ethane only), physical properties, chemical reactions including free radical mechanism of halogenation, combustion and pyrolysis.
• Alkanes-Nomenclature, structure of double bond (ethene), geometrical isomerism, physical properties, methods of preparation: chemical  reactions:  addition  of  hydrogen,  halogen,  water,  hydrogen  halides  (Markovnikov’s  addition  and  peroxide  effect), ozonolysis, oxidation, mechanism of electrophilic addition.
• Alkynes-Nomenclature, structure of triple bond (ethyne), physical properties, methods of preparation, chemical reactions: acidic character of alkynes, addition reaction of- hydrogen, halogens, hydrogen halides and water.
• Aromatic hydrocarbons- Introduction, IUPAC nomenclature; Benzene; resonance, aromaticity; chemical properties: mechanism of electrophilic substitution- Nitration sulphonation, halogenation, Friedel Craft’s alkylation and acylation; directive influence of functional group in mono-substituted benzene; carcinogenicity and toxicity.
UNIT XIV: Environmental Chemistry
• Environmental pollution: Air, water and soil pollution, chemical reactions in atmosphere, smogs, major atmospheric pollutants; acid rain ozone and its reactions, effects of depletion of ozone layer, greenhouse effect and global warming-pollution due to industrial wastes; green chemistry as an alternative tool for reducing pollution, strategy for control of environmental pollution.

CONTENTS OF CLASS XII SYLLABUS
UNIT I: Solid State
• Classification of solids based on different binding forces; molecular, ionic covalent and metallic solids, amorphous and crystalline solids (elementary idea), unit cell in two dimensional and three dimensional lattices, calculation of density of unit cell, packing in  solids,  packing  efficiency,  voids,  number  of  atoms  per  unit  cell  in  a  cubic  unit  cell,  point  defects,  electrical  and  magnetic properties, Band theory of metals, conductors, semiconductors and insulators.
UNIT II: Solutions
• Types  of  solutions,  expression  of  concentration  of  solutions  of  solids  in  liquids,  solubility  of  gases  in  liquids,  solid  solutions, Colligative properties- relative lowering of vapour pressure, Raoult’s law, elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular masses using colligative properties abnormal molecular mass. VanHoff  factor.
UNIT III: Electrochemistry
• Redox  reactions,  conductance  in  electrolytic  solutions,  specific  and  molar  conductivity  variation  of  conductivity  with concentration, kohlrausch’s Law, electrolysis and Laws of electrolysis (elementary idea), dry cell- electrolytic cells and Galvanic cells; lead accumulator, EMF of a cell, standard electrode potential, Relation between Gibbs energy change and EMF of a cell, fuel cells; corrosion.
UNIT IV: Chemical Kinetics
• Rate of a reaction (average and instantaneous), factors affecting rates of reaction; concentration, temperature, catalyst; order and molecularity of a reaction; rate law and specific rate constant, integrated rate equations and half life (only for zero and first order  reactions);  concept  of  collision  theory  (  elementary  idea,  no  mathematical  treatment).   Activation  energy, Arrhenius equation.
UNIT V: Surface Chemistry
• Adsorption-physisorption  and  chemisorption;  factors  affecting  adsorption  of  gases  on  solids,  catalysis  homogeneous  and heterogeneous,  activity  and  selectivity:  enzyme  catalysis;  colloidal  state:  distinction  between  true  solutions,  colloids  and suspensions; lyophillic, lyophobic multimolecular and macromolecular colloids; properties of colloids; Tyndall effect, Brownian movement, electrophoresis, coagulation; emulsions- types of emulsions.
UNIT VI: General Principles and Processes of Isolation of Elements
• Principles  and  methods  of  extraction- concentration,  oxidation,  reduction  electrolytic  method  and  refining;  occurrence  and principles of extraction of aluminium, copper, zinc and iron.
UNIT VII: p-Block Elements
• Group 15 elements: General introduction, electronic configuration, occurrence, oxidation states, trends in physical and chemical properties; preparation and properties of ammonia and nitric acid, oxides of nitrogen (structure only); Phosphorous- allotropic forms; compounds of phosphorous: preparation and properties of phosphine, halides (PCI3, PCI5) and oxoacids (elementary idea
only).
• Group 16 elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; dioxygen preparation, properties and uses; classification of oxides; ozone. Sulphur allotropic forms; compounds of sulphur: preparation, preparation, properties and uses of sulphur dioxide; sulphuric acid: industrial process of manufacture, properties and uses, oxoacids of sulphur (structures only).
• Group 17 elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; compounds of halogens: preparation, properties and uses of chlorine and hydrochloric acid, interhalogen compounds oxoacids of halogens (structures only).
• Group 18 elements: General introduction, electronic configuration, occurrence, trends in physical and chemical properties, uses.
UNIT VIII: d and f Block Elements
• General  introduction,  electronic  configuration,  characteristics  of  transition  metals,  general  trends  in  properties  of  the  first row transition metals- metallic character, ionization enthalpy, oxidation states, ionic radii, color, catalytic property, magnetic properties, interstitial compounds, alloy formation. Preparation and properties of K2Cr2O7 and KMnO4.
• Lanthanoids-electronic configuration, oxidation states, chemical reactivity, and lanthanoid contraction and its consequences.
• Actinoids: Electronic configuration, oxidation states and comparison with lanthanoids.
UNIT IX: Coordination Compounds
• Coordination  compounds: Introduction,  ligands, coordination  number, color,  magnetic  properties  and  shapes,  IUPAC nomenclature of mononuclear coordination compounds, isomerism (structural and stereo) bonding, Werner’s theory VBT,CFT; importance of coordination compounds (in qualitative analysis, biological systems).
UNIT X: Haloalkanes and Haloarenes
• Haloalkanes: Nomenclature, nature of C-X bond, physical and chemical properties, mechanism of substitution reactions. Optical rotation.
• Haloarenes: Nature of C-X bond, substitution reactions (directive influence of halogen for monosubstituted compounds only).
• Uses and environment effects of dichloromethane, trichloromethane, tetrachloromethane, iodoform, freons, DDT.
UNIT XI: Alcohols, Phenols and Ethers
• Alcohols: Nomenclature, methods of preparation, physical and chemical properties (of primary alcohols only); identification of primary, secondary and tertiary alcohols; mechanism of dehydration, uses with special reference to methanol and ethanol.
• Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of phenol, electrophillic substitution reactions, uses of phenols.
• Ethers: Nomenclature, methods of preparation, physical and chemical properties uses.
UNIT XII: Aldehydes, Ketones and Carboxylic Acids
• Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical and chemical properties; and mechanism of nucleophilic addition, reactivity of alpha hydrogen in aldehydes; uses.
• Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical properties; uses.
UNIT XIII: Organic Compounds Containing Nitrogen
• Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical properties, uses, identification of primary secondary and tertiary amines.
• Cyanides and Isocyanides- will be mentioned at relevant places.
• Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.
UNIT XIV: Biomolecules
• Carbohydrates- Classification (aldoses and ketoses), monosaccharide (glucose and fructose), D.L. configuration, oligosaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose, glycogen): importance.
• Proteins- Elementary  idea  of     amino  acids,  peptide  bond,  polypeptides,  proteins,  primary  structure,  secondary  structure, tertiary structure and quaternary structure (qualitative idea only), denaturation of proteins; enzymes.
• Hormones- Elementary idea (excluding structure).
• Vitamins: Classification and function.
• Nucleic Acids: DNA and RNA
UNIT XV: Polymers
• Classification- Natural and synthetic, methods of polymerization (addition and condensation), copolymerization. Some important polymers: natural and synthetic like polyesters, Bakelite; rubber, Biodegradable and non-biodegradable polymers.
UNIT XVI: Chemistry in Everyday Life
• Chemicals  in  medicines-  analgesics,  tranquilizers,  antiseptics,  disinfectants,  antimicrobials,  anti fertility  drugs,  antibiotics, antacids, antihistamines.
• Chemicals in food- preservatives, artificial sweetening agents, elementary idea of antioxidants.
• Cleansing agents- soaps and detergents, cleansing action.
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